Electron diffraction and matter waves Cambridge International AS & A Level Physics revision
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In plain words
If light, a wave, can behave like particles, can particles behave like waves? They can. Fire a beam of electrons through a thin layer of graphite and they make rings on a screen: a diffraction pattern, the signature of a wave.
Three things to know
- Wave–particle duality: light shows wave behaviour (interference, diffraction) and particle behaviour (the photoelectric effect). So do electrons and other particles.
- Every moving particle has a de Broglie wavelength λ = h ÷ p, where p = mv is its momentum.
- Electron diffraction is the evidence. Speeding the electrons up gives them more momentum and a shorter wavelength, so the rings get smaller.
Worked example
Find the de Broglie wavelength of an electron moving at 2.0 × 10⁶ m/s. (Mass of an electron = 9.11 × 10⁻³¹ kg.)
- Momentum p = mv = 9.11 × 10⁻³¹ × 2.0 × 10⁶ = 1.82 × 10⁻²⁴ kg m/s.
- λ = h ÷ p = 6.63 × 10⁻³⁴ ÷ 1.82 × 10⁻²⁴.
- = 3.6 × 10⁻¹⁰ m, about the spacing of the atoms in a crystal.
Tips and tricks
- A faster or heavier particle has a shorter wavelength: λ is inversely proportional to momentum.
- Diffraction only shows up when the wavelength is about the size of the gap. That is why electrons diffract through crystals and footballs don't diffract through doorways.
It lands in your notebook with its questions as flashcards.
Electron diffraction and matter waves: 5 questions and answers
These are the quiz’s questions. Do the quiz first, then come back here for the ones that got you.
What is the de Broglie wavelength of a particle of momentum p?
More momentum, shorter wavelength.
What is the evidence that electrons have wave properties?
Diffraction is something only waves do.
A proton and an electron move at the same speed. Which has the longer de Broglie wavelength?
The electron has far less momentum.
The speed of an electron is doubled. What happens to its de Broglie wavelength?
λ = h ÷ mv.
Which pair of observations shows that light has both wave and particle properties?
Diffraction needs waves; the photoelectric effect needs photons.
Quiz
5 questions
Tap an answer and you’ll see straight away whether it’s right, and why.
Worksheet
3 questions, 7 marks. Write your answers on paper, then check them.
Electron diffraction and matter waves
Cambridge International AS & A Level Physics 9702 · 7 marks · papermunch.org
Name ______________________________ Date ______________
State what electron diffraction shows about electrons.[2]
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That they have wave properties: they behave as waves as well as particles.
Find the de Broglie wavelength of a 0.060 kg tennis ball moving at 50 m/s.[2]
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2.2 × 10⁻³⁴ m. 6.63 × 10⁻³⁴ ÷ 3.0. It is far too small ever to notice.
The accelerating p.d. in an electron diffraction tube is increased. State and explain what happens to the rings.[3]
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They get smaller. The electrons are faster, so they have more momentum and a shorter de Broglie wavelength, and a shorter wavelength is diffracted through smaller angles.
Answers: Electron diffraction and matter waves
- 1. That they have wave properties: they behave as waves as well as particles.
- 2. 2.2 × 10⁻³⁴ m. 6.63 × 10⁻³⁴ ÷ 3.0. It is far too small ever to notice.
- 3. They get smaller. The electrons are faster, so they have more momentum and a shorter de Broglie wavelength, and a shorter wavelength is diffracted through smaller angles.



