Covalent bonding and simple molecules Cambridge IGCSE Chemistry revision

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In plain words

Two non-metal atoms both want more electrons, so neither will give any away. Instead they share. A shared pair of electrons holds the two atoms together: a covalent bond. A few atoms joined this way make a small molecule, such as water or methane.

Three things to know

  1. A covalent bond is a pair of electrons shared between two non-metal atoms. Sharing gives each atom a full outer shell.
  2. Simple molecules such as H₂, Cl₂, H₂O, CH₄, NH₃ and CO₂ have low melting and boiling points, because the forces between the molecules are weak. The covalent bonds themselves are strong.
  3. They do not conduct electricity: there are no ions and no free electrons. O₂ and CO₂ have double bonds; N₂ has a triple bond.

Tips and tricks

  • Low melting point? Blame the weak forces between the molecules. The covalent bonds inside each molecule are strong and don't break when it melts.
  • In a dot-and-cross diagram, count the electrons round each atom at the end: 8 in the outer shell (2 for hydrogen).
6 questions, about 2 minutes.

It lands in your notebook with its questions as flashcards.

Covalent bonding and simple molecules: 6 questions and answers

These are the quiz’s questions. Do the quiz first, then come back here for the ones that got you.

  1. How is a covalent bond formed?
    • by transferring electrons
    • by sharing a pair of electrons (the answer)
    • by losing protons
    • by attraction between ions

    Each atom counts the shared pair towards its outer shell.

  2. Which substance has covalent bonds?
    • sodium chloride
    • magnesium oxide
    • water (the answer)
    • copper

    Water is made of non-metals only.

  3. Why do simple molecular substances have low boiling points?
    • Their covalent bonds are weak.
    • The forces between their molecules are weak. (the answer)
    • Their atoms are small.
    • They contain ions.

    Boiling separates the molecules; it does not break the bonds inside them.

  4. How many pairs of electrons are shared in a nitrogen molecule, N₂?
    • 1
    • 2
    • 3 (the answer)
    • 4

    Nitrogen atoms are joined by a triple bond.

  5. Why do simple covalent substances not conduct electricity?
    • Their molecules are too heavy.
    • They have no ions or free electrons to carry charge. (the answer)
    • They are always solids.
    • Their bonds are too strong.

    Something charged has to be able to move.

  6. How many covalent bonds does the carbon atom form in methane, CH₄?
    • 1
    • 2
    • 3
    • 4 (the answer)

    Carbon has four outer electrons and shares each of them.

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