The blast furnace and aluminium Cambridge IGCSE Chemistry (9–1) revision

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In plain words

Iron is made in a blast furnace: a tower as tall as a block of flats, fed with iron ore, coke and limestone at the top and blasted with hot air at the bottom. Aluminium is made by passing a huge electric current through its molten ore.

Three things to know

  1. Blast furnace: coke burns to give heat and carbon dioxide (C + O₂ → CO₂), which reacts with more coke to make carbon monoxide (CO₂ + C → 2CO). Carbon monoxide reduces the ore, hematite: Fe₂O₃ + 3CO → 2Fe + 3CO₂.
  2. Limestone removes sandy impurities. It decomposes (CaCO₃ → CaO + CO₂) and the calcium oxide reacts with silicon dioxide to form slag (CaO + SiO₂ → CaSiO₃).
  3. Aluminium: its ore, bauxite, is purified to aluminium oxide, which is dissolved in molten cryolite and electrolysed. Aluminium forms at the cathode and oxygen at the carbon anodes, which burn away and have to be replaced.

Tips and tricks

  • The reducing agent in the blast furnace is carbon monoxide, not carbon. This is asked a lot.
  • Cryolite lowers the temperature needed, which saves energy.
6 questions, about 2 minutes.

It lands in your notebook with its questions as flashcards.

The blast furnace and aluminium: 6 questions and answers

These are the quiz’s questions. Do the quiz first, then come back here for the ones that got you.

  1. What is the main ore of iron?
    • bauxite
    • hematite (the answer)
    • cryolite
    • limestone

    Hematite is mostly iron(III) oxide.

  2. What reduces the iron(III) oxide in a blast furnace?
    • limestone
    • oxygen
    • carbon monoxide (the answer)
    • slag

    Fe₂O₃ + 3CO → 2Fe + 3CO₂.

  3. What is limestone added to the blast furnace for?
    • to make it hotter
    • to remove sandy impurities as slag (the answer)
    • to reduce the ore
    • to add carbon to the iron

    It forms calcium oxide, which reacts with silicon dioxide.

  4. What is the main ore of aluminium?
    • bauxite (the answer)
    • hematite
    • cryolite
    • rock salt

    It is purified to give aluminium oxide.

  5. Why are the anodes in the aluminium cell replaced often?
    • They melt.
    • They dissolve in the cryolite.
    • They react with the oxygen formed and burn away. (the answer)
    • They become coated with aluminium.

    Hot carbon and oxygen make carbon dioxide.

  6. At which electrode does aluminium form?
    • the anode
    • the cathode (the answer)
    • both
    • neither

    Aluminium ions are positive, so they go to the negative electrode.

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