Polymers and plastics Cambridge IGCSE Chemistry (9–1) revision

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In plain words

A polymer is a very long molecule made by joining thousands of small ones, like a chain of paper clips. The small molecules are monomers. Plastics are polymers, and so are the proteins in your body.

Three things to know

  1. Addition polymerisation: alkene monomers join when their double bonds open, and the polymer is the only product. Ethene makes poly(ethene).
  2. Condensation polymerisation: two kinds of monomer join, and a small molecule such as water is lost each time. Polyesters and polyamides (nylon) are made this way. Proteins are natural polyamides, made from amino acids.
  3. Most plastics do not break down, so they fill landfill sites and pile up in the oceans. Burning them can give off toxic gases.

Worked example

Name the polymer made from the monomer propene, and the type of polymerisation.

  1. Put "poly" in front and the monomer's name in brackets: poly(propene).
  2. Propene is an alkene, with a C=C double bond that opens up.
  3. Poly(propene), by addition polymerisation.

Tips and tricks

  • To draw a repeat unit: change the double bond to a single bond, and put a bond out of each side through brackets.
  • Addition: one product only. Condensation: the polymer plus a small molecule, usually water.
6 questions, about 2 minutes.

It lands in your notebook with its questions as flashcards.

Polymers and plastics: 6 questions and answers

These are the quiz’s questions. Do the quiz first, then come back here for the ones that got you.

  1. What is the monomer used to make poly(ethene)?
    • ethane
    • ethene (the answer)
    • ethanol
    • methane

    The polymer is named after its monomer.

  2. What must a monomer have to take part in addition polymerisation?
    • an –OH group
    • a carbon–carbon double bond (the answer)
    • an ionic bond
    • a ring of atoms

    The double bond opens so the monomers can link up.

  3. Which small molecule is usually lost in condensation polymerisation?
    • water (the answer)
    • carbon dioxide
    • hydrogen
    • methane

    One is lost each time two monomers join.

  4. What type of polymer is nylon?
    • a polyester
    • a polyamide (the answer)
    • an addition polymer
    • a protein

    It is made by condensation polymerisation.

  5. Why do plastics cause pollution?
    • They dissolve in water.
    • They are not biodegradable. (the answer)
    • They are magnetic.
    • They react with air.

    Microbes cannot break most of them down.

  6. Proteins are polymers of what?
    • sugars
    • alkenes
    • amino acids (the answer)
    • fatty acids

    Amino acids join by condensation to make proteins.

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