Ions and ionic bonding Cambridge IGCSE Co-ordinated Sciences (9–1) revision

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In plain words

Metals want to lose their outer electrons; non-metals want to gain some. When they meet, the metal hands electrons over. Now one is a positive ion and the other a negative ion, and opposite charges attract strongly. Millions of them stack up in a giant lattice. That attraction is the ionic bond.

Three things to know

  1. Metal atoms lose their outer electrons and become positive ions. Non-metal atoms gain electrons and become negative ions. Both end up with full outer shells.
  2. An ionic bond is the strong electrostatic attraction between oppositely charged ions. The ions are arranged in a giant lattice.
  3. Ionic compounds have high melting points, and conduct electricity when molten or dissolved (the ions can move) but not when solid.

Worked example

Work out the formula of aluminium chloride. (Ions: Al³⁺ and Cl⁻.)

  1. The charges must add up to zero.
  2. One Al³⁺ has a charge of 3+, so it needs three Cl⁻ ions (3−).
  3. AlCl₃.

Tips and tricks

  • To write a formula, swap the sizes of the charges: Al³⁺ and O²⁻ give Al₂O₃. Then cancel down if you can.
  • Conducts when molten or dissolved "because the ions are free to move". Never say electrons for an ionic compound.
6 questions, about 2 minutes.

It lands in your notebook with its questions as flashcards.

Ions and ionic bonding: 6 questions and answers

These are the quiz’s questions. Do the quiz first, then come back here for the ones that got you.

  1. What is the charge on the ion formed by a Group 2 metal?
    • 1+
    • 2+ (the answer)
    • 2−
    • 6−

    It loses its two outer electrons.

  2. What holds the ions together in an ionic compound?
    • shared pairs of electrons
    • attraction between opposite charges (the answer)
    • delocalised electrons
    • weak forces between molecules

    Positive and negative ions attract each other strongly.

  3. Which substance is ionic?
    • water
    • methane
    • potassium bromide (the answer)
    • carbon dioxide

    It is made from a metal and a non-metal.

  4. What is the formula of calcium oxide? (Ions: Ca²⁺ and O²⁻.)
    • CaO (the answer)
    • Ca₂O
    • CaO₂
    • Ca₂O₃

    One 2+ ion balances one 2− ion.

  5. When do ionic compounds conduct electricity?
    • when solid
    • when molten or dissolved in water (the answer)
    • never
    • only when cold

    The ions must be free to move.

  6. What is the formula of aluminium oxide? (Ions: Al³⁺ and O²⁻.)
    • AlO
    • Al₃O₂
    • Al₂O₃ (the answer)
    • AlO₃

    Two 3+ ions (6+) balance three 2− ions (6−).

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