Titrations Cambridge IGCSE Co-ordinated Sciences (9–1) revision

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In plain words

A titration finds exactly how much acid cancels out an alkali. You drip acid from a burette into the alkali, with an indicator in it, and stop the instant the colour changes. That instant is called the end-point.

Three things to know

  1. Measure out the alkali with a pipette into a conical flask. Add a few drops of indicator. Add acid from the burette, swirling, until the indicator just changes colour.
  2. Methyl orange is yellow in alkali and red in acid. Thymolphthalein is blue in alkali and colourless in acid; phenolphthalein is pink in alkali and colourless in acid.
  3. Do a rough run first, then repeat adding the acid drop by drop near the end, until two results agree closely.

Worked example

A burette reads 1.20 cm³ at the start of a titration and 24.70 cm³ at the end. How much acid was added?

  1. Volume added = final reading − start reading.
  2. = 24.70 − 1.20.
  3. = 23.50 cm³.

Tips and tricks

  • Read a burette from the bottom of the curve (the meniscus), with your eye level with it.
  • Stand the flask on a white tile so the colour change is easy to see, and swirl after every addition.
5 questions, about 2 minutes.

It lands in your notebook with its questions as flashcards.

Titrations: 5 questions and answers

These are the quiz’s questions. Do the quiz first, then come back here for the ones that got you.

  1. What is the end-point of a titration?
    • when the burette is empty
    • when the indicator just changes colour (the answer)
    • when the flask is full
    • when the solution boils

    At that point the acid has exactly neutralised the alkali.

  2. Which piece of apparatus is the acid added from?
    • a pipette
    • a burette (the answer)
    • a measuring cylinder
    • a beaker

    A burette lets you add any volume and read it accurately.

  3. Why is the flask swirled during a titration?
    • to cool it
    • to mix the solutions (the answer)
    • to dissolve the glass
    • to remove bubbles

    Otherwise the colour change is patchy and the end-point is missed.

  4. Why is universal indicator not used in titrations?
    • It is too expensive.
    • Its colour changes gradually, so there is no sharp end-point. (the answer)
    • It is not affected by acids.
    • It is a solid.

    A single, sudden colour change is needed.

  5. After a rough titration, how should the acid be added near the end-point?
    • all at once
    • a drop at a time (the answer)
    • from a beaker
    • without swirling

    One drop can be enough to change the colour.

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