Rates of reaction Cambridge IGCSE Co-ordinated Sciences (Double Award) revision

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In plain words

For particles to react they have to bump into each other, and bump hard enough. Anything that makes those useful collisions happen more often speeds the reaction up: more particles in the space, smaller pieces, more heat, or a catalyst to make it easier.

Three things to know

  1. A reaction goes faster with a higher concentration (or gas pressure), a higher temperature, a larger surface area (smaller pieces) or a catalyst.
  2. Collision theory: particles must collide with at least the activation energy. A faster reaction means more successful collisions each second.
  3. A catalyst speeds up a reaction without being used up, by lowering the activation energy. Follow a rate by measuring the gas given off, or the mass lost, over time.

Worked example

A reaction gives off 60 cm³ of gas in the first 20 s. Find the average rate.

  1. Rate = amount of product ÷ time.
  2. = 60 ÷ 20.
  3. = 3 cm³/s.

Tips and tricks

  • The full answer for temperature has two parts: the particles collide more often, and more of the collisions have enough energy.
  • On a graph a steeper line means a faster reaction, and where the line goes flat the reaction has finished.
6 questions, about 2 minutes.

It lands in your notebook with its questions as flashcards.

Rates of reaction: 6 questions and answers

These are the quiz’s questions. Do the quiz first, then come back here for the ones that got you.

  1. Which change does not speed up a reaction between a solid and an acid?
    • heating the acid
    • using more concentrated acid
    • using larger lumps of the solid (the answer)
    • adding a catalyst

    Larger lumps have a smaller surface area.

  2. What is true of a catalyst?
    • It is used up in the reaction.
    • It speeds up the reaction and is not used up. (the answer)
    • It slows the reaction down.
    • It makes more product.

    It can be recovered unchanged at the end.

  3. Why does a more concentrated solution react faster?
    • The particles are bigger.
    • The particles have more energy.
    • There are more particles in the same volume, so they collide more often. (the answer)
    • The activation energy is higher.

    More frequent collisions means a faster reaction.

  4. How does a catalyst work?
    • It heats the reaction.
    • It lowers the activation energy. (the answer)
    • It adds more reactant.
    • It raises the pressure.

    More of the collisions are then successful.

  5. On a graph of volume of gas against time, what does a steeper line show?
    • a faster reaction (the answer)
    • a slower reaction
    • more gas at the end
    • a higher temperature at the end

    The gas is being made more quickly.

  6. The line on a rate graph goes flat. What has happened?
    • The reaction has speeded up.
    • One of the reactants has been used up. (the answer)
    • The catalyst has been used up.
    • The gas has escaped.

    No more product is being made.

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