The photoelectric effect Edexcel International A Level Physics revision

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In plain words

Shine ultraviolet light on zinc and electrons come off. Shine red light on it, however bright, and nothing happens. A wave can't explain that. Einstein's answer was that each electron is knocked out by one photon acting alone: either that one packet has enough energy, or it doesn't.

4 things to know

  1. Photoelectric emission: electrons are released from a metal surface when radiation of a high enough frequency shines on it. Each electron absorbs one photon.
  2. The work function φ is the minimum energy needed to free an electron from the surface. The threshold frequency f₀ is the lowest frequency that frees any: hf₀ = φ. (The threshold wavelength is the longest wavelength that works.)
  3. Einstein's equation: hf = φ + ½mv²max. The photon's energy pays the work function, and what is left over is the electron's maximum kinetic energy.
  4. Making the light brighter at the same frequency means more photons each second, so more electrons each second (a bigger photoelectric current), but their maximum kinetic energy stays the same.

Worked example

Light of wavelength 400 nm falls on a metal with a work function of 2.0 eV. Find the maximum kinetic energy of the photoelectrons.

  1. Photon energy = hc ÷ λ = 6.63 × 10⁻³⁴ × 3.00 × 10⁸ ÷ 4.00 × 10⁻⁷ = 4.97 × 10⁻¹⁹ J.
  2. In electronvolts: 4.97 × 10⁻¹⁹ ÷ 1.60 × 10⁻¹⁹ = 3.1 eV.
  3. Maximum kinetic energy = 3.1 − 2.0 = 1.1 eV (1.8 × 10⁻¹⁹ J).

Tips and tricks

  • Intensity decides how many electrons. Frequency decides how energetic they are. Keep the two apart.
  • Have the photon energy and the work function in the same units, both joules or both electronvolts, before you subtract.
5 questions, about 2 minutes.

It lands in your notebook with its questions as flashcards.

The photoelectric effect: 5 questions and answers

These are the quiz’s questions. Do the quiz first, then come back here for the ones that got you.

  1. What is the work function of a metal?
    • the maximum kinetic energy of an emitted electron
    • the minimum energy needed to free an electron from its surface (the answer)
    • the energy of one photon
    • the threshold wavelength

    Photons with less energy than this free nothing.

  2. Light above the threshold frequency is made brighter. What happens?
    • The electrons come off with more kinetic energy.
    • More electrons are emitted each second. (the answer)
    • The threshold frequency rises.
    • Nothing changes.

    More photons arrive, and each one can free one electron.

  3. The frequency of the light is increased, above the threshold. What happens to the photoelectrons?
    • Their maximum kinetic energy increases. (the answer)
    • Their maximum kinetic energy decreases.
    • Fewer of them have any energy.
    • The work function increases.

    Each photon brings more energy, and the work function is unchanged.

  4. Which observation shows that light behaves as particles?
    • interference
    • diffraction
    • the photoelectric effect (the answer)
    • polarisation

    The others are evidence that light is a wave.

  5. Light below the threshold frequency is made much brighter. What happens?
    • Still no electrons are emitted. (the answer)
    • A few electrons are emitted.
    • Electrons are emitted after a delay.
    • Electrons are emitted with low energy.

    No single photon has enough energy.

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