Electron diffraction and matter waves Edexcel International A Level Physics revision

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In plain words

If light, a wave, can behave like particles, can particles behave like waves? They can. Fire a beam of electrons through a thin layer of graphite and they make rings on a screen: a diffraction pattern, the signature of a wave.

Three things to know

  1. Wave–particle duality: light shows wave behaviour (interference, diffraction) and particle behaviour (the photoelectric effect). So do electrons and other particles.
  2. Every moving particle has a de Broglie wavelength λ = h ÷ p, where p = mv is its momentum.
  3. Electron diffraction is the evidence. Speeding the electrons up gives them more momentum and a shorter wavelength, so the rings get smaller.

Worked example

Find the de Broglie wavelength of an electron moving at 2.0 × 10⁶ m/s. (Mass of an electron = 9.11 × 10⁻³¹ kg.)

  1. Momentum p = mv = 9.11 × 10⁻³¹ × 2.0 × 10⁶ = 1.82 × 10⁻²⁴ kg m/s.
  2. λ = h ÷ p = 6.63 × 10⁻³⁴ ÷ 1.82 × 10⁻²⁴.
  3. = 3.6 × 10⁻¹⁰ m, about the spacing of the atoms in a crystal.

Tips and tricks

  • A faster or heavier particle has a shorter wavelength: λ is inversely proportional to momentum.
  • Diffraction only shows up when the wavelength is about the size of the gap. That is why electrons diffract through crystals and footballs don't diffract through doorways.
5 questions, about 2 minutes.

It lands in your notebook with its questions as flashcards.

Electron diffraction and matter waves: 5 questions and answers

These are the quiz’s questions. Do the quiz first, then come back here for the ones that got you.

  1. What is the de Broglie wavelength of a particle of momentum p?
    • hp
    • h ÷ p (the answer)
    • p ÷ h
    • h ÷ p²

    More momentum, shorter wavelength.

  2. What is the evidence that electrons have wave properties?
    • the photoelectric effect
    • electron diffraction (the answer)
    • line spectra
    • radioactive decay

    Diffraction is something only waves do.

  3. A proton and an electron move at the same speed. Which has the longer de Broglie wavelength?
    • the proton
    • the electron (the answer)
    • they are equal
    • neither has one

    The electron has far less momentum.

  4. The speed of an electron is doubled. What happens to its de Broglie wavelength?
    • It halves. (the answer)
    • It doubles.
    • It stays the same.
    • It falls to a quarter.

    λ = h ÷ mv.

  5. Which pair of observations shows that light has both wave and particle properties?
    • diffraction and the photoelectric effect (the answer)
    • diffraction and interference
    • reflection and refraction
    • polarisation and interference

    Diffraction needs waves; the photoelectric effect needs photons.

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