Rates of reaction Edexcel International GCSE Science (Double Award) revision
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In plain words
For particles to react they have to bump into each other, and bump hard enough. Anything that makes those useful collisions happen more often speeds the reaction up: more particles in the space, smaller pieces, more heat, or a catalyst to make it easier.
Three things to know
- A reaction goes faster with a higher concentration (or gas pressure), a higher temperature, a larger surface area (smaller pieces) or a catalyst.
- Collision theory: particles must collide with at least the activation energy. A faster reaction means more successful collisions each second.
- A catalyst speeds up a reaction without being used up, by lowering the activation energy. Follow a rate by measuring the gas given off, or the mass lost, over time.
Worked example
A reaction gives off 60 cm³ of gas in the first 20 s. Find the average rate.
- Rate = amount of product ÷ time.
- = 60 ÷ 20.
- = 3 cm³/s.
Tips and tricks
- The full answer for temperature has two parts: the particles collide more often, and more of the collisions have enough energy.
- On a graph a steeper line means a faster reaction, and where the line goes flat the reaction has finished.
It lands in your notebook with its questions as flashcards.
Rates of reaction: 6 questions and answers
These are the quiz’s questions. Do the quiz first, then come back here for the ones that got you.
Which change does not speed up a reaction between a solid and an acid?
Larger lumps have a smaller surface area.
What is true of a catalyst?
It can be recovered unchanged at the end.
Why does a more concentrated solution react faster?
More frequent collisions means a faster reaction.
How does a catalyst work?
More of the collisions are then successful.
On a graph of volume of gas against time, what does a steeper line show?
The gas is being made more quickly.
The line on a rate graph goes flat. What has happened?
No more product is being made.
Quiz
6 questions
Tap an answer and you’ll see straight away whether it’s right, and why.
Worksheet
4 questions, 9 marks. Write your answers on paper, then check them.
Rates of reaction
Edexcel International GCSE Science (Double Award) 4SD0 · 9 marks · papermunch.org
Name ______________________________ Date ______________
Explain why powdered calcium carbonate reacts faster with acid than lumps of the same mass.[2]
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The powder has a larger surface area, so the acid particles collide with it more often.
Explain why raising the temperature increases the rate of a reaction.[3]
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The particles have more energy and move faster, so they collide more often, and more of the collisions have at least the activation energy.
State what is meant by a catalyst.[2]
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A substance that increases the rate of a reaction and is not used up (it is chemically unchanged at the end).
A reaction produces 48 cm³ of gas in the first 20 s. Calculate the average rate of reaction.[2]
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2.4 cm³/s. 48 ÷ 20.
Answers: Rates of reaction
- 1. The powder has a larger surface area, so the acid particles collide with it more often.
- 2. The particles have more energy and move faster, so they collide more often, and more of the collisions have at least the activation energy.
- 3. A substance that increases the rate of a reaction and is not used up (it is chemically unchanged at the end).
- 4. 2.4 cm³/s. 48 ÷ 20.



